The Ferrari driver produced a dramatic final lap in qualifying on Saturday, recovering from a major mistake that appeared to have allowed Max Verstappen to take pole.
He did, however, complain of a lack of power in the final moments, which made for a fascinating weekend.
Carlos Sainz, George Russell and Lewis Hamilton also impressed in qualifying heading into the sixth race of the season.
CLICK HERE TO FOLLOW THE F1 SPANISH GRAND PRIX LIVE!
How can I watch the Spanish F1 Grand Prix?
TV channel: The race will be shown live on Sky Sports F1, with coverage starting at 12.30pm before the lights go out at 2pm.
Direct: Sky Sports subscribers can also tune in online via the Sky Go app.
Free Highlights: Channel 4 will broadcast all the highlights of the race free-to-air at 6.30pm on Sunday evening.
Live Blog: You can catch up on the race in real time via Standard Sport’s live blog, with Matt Majendie on the track to provide expert analysis.